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Thermodynamics of adsorption of imidacloprid at constant charge hydrophobic surfaces: physicochemical aspects of bioenvironmental activity.

Giannakopoulos E, Stivaktakis P, Deligiannakis Y

Department of Environmental & Natural Resources Management, University of Ioannina, Seferi 2, Agrinio, Greece.

Adsorption of the insecticide 1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine (Imidacloprid) on the hanging mercury drop electrode (HMDE) surface was studied by temperature-dependent stripping voltammetry (TD-SV). At near physiological pH, under reducing conditions, the Gibbs free energy of adsorption, DeltaGADS, shows two distinct temperature-dependent regimes. (a) At 0 degrees < T < 10 degrees C a temperature-independent mechanism occurs with a constant DeltaGADS = -40.5 kJ/mol, resulting in strong chemisorption at high surface coverage. For T < 10 degrees C a considerable enthalpy gain is estimated, and this represents the driving force for the adsorption of Imidacloprid onto the electrode surface. (b) At T > 10 degrees C a temperature-dependent mechanism is operative with DeltaGADS/DeltaT = -91.4 J/K mol, resulting in a rapid weakening of adsorption and low surface coverage. On the basis of the present findings we suggest that the strong chemisorption at T < 10 degrees C at physiological pH under reducing conditions is related to the high specific insecticide activity of Imidacloprid in cool-blooded insects as contrasted to its low efficiency in warm-blooded organisms.

Published 1 April 2008 in Langmuir, 24(8): 3955-9.
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